Silica aerogels modified with vinyl, epoxide, methacrylate moieties for the removal of ciprofloxacin by adsorption from water

Abstract

Water pollution caused by antibiotic effluents, particularly ciprofloxacin is a growing environmental concern. To address this problem, silica aerogels containing vinyl, epoxide, or methacrylate organic functionalities were synthesized through facile sol-gel synthesis under ambient conditions and employed as ciprofloxacin adsorbents in this study. The physicochemical and structural features of the materials were characterized using conventional and complementary techniques. Structural characterization confirmed the successful chemical functionalization of the silica surface for all samples. Similar to the pristine aerogel, the vinyl-functionalized aerogel displayed a typical mesoporous network, whereas epoxide and methacrylate functionalization caused dominantly macroporous structures. Batchwise sorption experiments were performed under different operating conditions. The results of the equilibrium and kinetic adsorption studies showed excellent alignment with the Langmuir isotherm and pseudo-second-order kinetic models, respectively. Under optimum conditions (C0 = 100 mg/L, mads/Vsoln = 0.5, pH=6, t = 90 min), the adsorption capacities of ciprofloxacin onto vinyl, epoxide, and methacrylatemodified aerogels were 62.7, 45.8 and 47.8 mg/g, respectively. Despite of the differences at micro- meso- and macrostructure level, obtaining similar adsorptive performances confirms that mechanism of sorption is not only relied on pore filling but also controlled by molecular interactions. The adsorbents also exhibited repetable sorption performance for at least six cycles.Ege University Office of Scientific Research Projects [23943]; CERIC-ERIC Consortium [20232184]; Austrian Federal Ministry of Education, Science and Research; Graz University of Technology; University of Graz; Anton Paar GmbHThis study was financially supported by the Ege University Office of Scientific Research Projects under Contract Number 23943. Authors thank the help of Manfred Kriechbaum for his assistance in the X-ray measurements. The authors acknowledge the CERIC-ERIC Consortium for the access to experimental SANS & SAXS facilities and financial support (Proposal ID 20232184) . The authors would like to acknowledge the use of the Somapp Lab, a core facility supported by the Austrian Federal Ministry of Education, Science and Research, the Graz University of Technology, the University of Graz, and Anton Paar GmbH