In this article, we generated a new operational matrix of integration using Clique polynomials of complete graphs and also introducing a new numerical technique to solve nonlinear Klein–Gordon equation. These equations describe a variety of physical phenomena such as ferroelectric and ferromagnetic domain walls, and DNA dynamics. We obtain an approximate solution for the nonlinear Klein–Gordon equation using the present method by transforming a system of nonlinear algebraic equations. The proposed scheme is applied to some examples and compared with another method in the literature that demonstrates the effectiveness of this method
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