Conformational Analysis of Tris(3-methylphenyl)phosphine and Its Chalcogenides

Ismagilova R.; Kuznetsova A.; Chachkov D.; Malysheva S.; Belogorlova N.; Vereshchagina Y.

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oai:dspace.kpfu.ru:net/148343

Conformational Analysis of Tris(3-methylphenyl)phosphine and Its Chalcogenides

Authors: Ismagilova R.
Kuznetsova A.
Chachkov D.
Malysheva S.
Belogorlova N.
Vereshchagina Y.
Publication date: 1 January 2018
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Abstract

© 2018, Pleiades Publishing, Ltd. Conformational analysis of tris(3-methylphenyl)phosphine and its chalcogenides has been performed by methods of dipole moments, IR spectroscopy, and quantum chemistry [DFT B3PW91/6-31G(df,p)]. In solution, these compounds exist as an equilibrium of conformers with gauche- and cis-arrangement of the substituents at the phosphorus atom relative to the P=X bond (X = lone electron pair, O, S, Se)

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Kazan Federal University Digital Repository

oai:dspace.kpfu.ru:net/148343

Last time updated on 06/05/2019

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