Phototransformations of azetidine radical cations stabilized in freonic matrices

Abstract

It has been established that transformations of azetidine radical cations observed in freonic matrices under the action of light with λ = 436 nm (T = 77 K) are associated with C-N bond cleavage which corresponds to the cyclic form yielding a mixture of open distonic C-centered radical cations of the following structure: ·CH2CH2CH=NH 2 + © 2014 Pleiades Publishing, Ltd

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This paper was published in Kazan Federal University Digital Repository.

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