Base-Promoted Consecutive Enolate Addition Reaction of [60]Fullerene with Ketones

Abstract

[60]Fullerene derivatives with novel 1,4,9,25- and 1,4,9,12-configurations were obtained by reactions of C-60 with aliphatic ketones and benzyl bromide under basic conditions. The structures of the products were determined by X-ray single-crystal diffraction and spectroscopic characterization. The reactions were rationalized by a monoenolate addition experiment and in situ vis-NIR spectroscopy

Similar works

Full text

thumbnail-image

Changchun Institute of Applied Chemistry, Chinese Academy Of Sciences

redirect
Last time updated on 13/03/2018

Having an issue?

Is data on this page outdated, violates copyrights or anything else? Report the problem now and we will take corresponding actions after reviewing your request.