[60]Fullerene derivatives with novel 1,4,9,25- and 1,4,9,12-configurations were obtained by reactions of C-60 with aliphatic ketones and benzyl bromide under basic conditions. The structures of the products were determined by X-ray single-crystal diffraction and spectroscopic characterization. The reactions were rationalized by a monoenolate addition experiment and in situ vis-NIR spectroscopy
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