Skip to main content
Article thumbnail
Location of Repository

An unsupported transition metal-lanthanide bond; synthesis and crystal structure of an Nd-Fe amido N-heterocyclic carbene complex

By Polly Arnold, J. McMaster and S.T. Liddle

Abstract

A salt-elimination reaction between the neodymium monoiodide [Nd(L)(N)(I)]2 [L = ButNCH2CH2{C(NCSiMe3CHNBut)}; N = N(SiMe3)2] and K[FeCp(CO)2] affords the first complex with an unsupported 4f–3d metal–metal bond that is sufficiently stable to be isolated; the bond is identified as principally ionic in nature by DFT calculations

Topics: donor-acceptor bonds; element thermochemistry; coordination chemistry; disruption enthalpies; molecular-structure; actinide; ligands; reactivity; catalysts; titanium
Year: 2009
DOI identifier: 10.1039/b819072k
OAI identifier: oai:www.era.lib.ed.ac.uk:1842/3014
Journal:

Suggested articles

Citations

  1. (2000). A doi
  2. (1989). Acta doi
  3. (2004). Gaussian 03, revision D01; Gaussian,
  4. (2009). Optimized Geometry for 1 Energy = -438.748302650 a.u.
  5. (2009). Supplementary Material (ESI) for Chemical Communications This journal is (c) The Royal Society of Chemistry
  6. (2001). Theoretical Chemistry Institute,

To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.