Location of Repository

Synthesis and structural characterisation of an yttrium-alkyl-alkylidene

By Polly Arnold, J.C. Green, J. McMaster and S.T. Liddle

Abstract

The first structurally authenticated yttrium-alkyl-alkylidene is reported; structural, spectroscopic, and theoretical analyses show that whilst the yttrium-alkylidene bond is short, it possesses a bond order less than one and is comparable to the Y-C-alkyl single bond within the same molecule

Topics: metal-carbon bonds; x-ray structures; nobel lecture; olefin-metathesis; transition-metal; carbene complex; reactivity; dft; bis(phosphinimino)methanides; stabilization
Year: 2008
DOI identifier: 10.1039/b719633d
OAI identifier: oai:www.era.lib.ed.ac.uk:1842/3016
Journal:

Suggested articles

Preview

Citations

  1. (2001). NBO 5.0.; Theoretical Chemistry Institute,
  2. (2008). Supplementary Material (ESI) for Chemical Communications This journal is (c) The Royal Society of Chemistry

To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.