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Biomimetic triblock copolymer membranes: from aqueous solutions to solid supports

By Alfredo González-Pérez, Valeria Castelletto, Ian Hamley and Pablo Taboada

Abstract

In the present paper, we studied the preparation of biomimetic triblock copolymer (ABA) membranes in aqueous solution and their deposition into solid supports. The self-assembly structures of the ABA in aqueous solution was investigated by using optical microscopy, dynamic light scattering, electron microscopy (EM) and SAXS. Spherical and tubular polymersomes were found at the highest concentrations investigated. The mechanism of deposition on solid supports (mica and glass) was elucidated by using atomic force microscopy (AFM). The deposition results in the formation of a uniform defect-free membrane at suitable polymer concentrations

Publisher: Royal Society of Chemistry
Year: 2011
OAI identifier: oai:centaur.reading.ac.uk:18659
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