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Dichlorido[2,4-dimethyl-N-(pyridin-2-yl­methyl­idene)aniline-κ2 N,N′]dimethyl­tin(IV)

By Sedigheh Loni, Mohamad Reza Talei Bavil Olyai, Fatemeh Roodbari and Behrouz Notash


The asymmetric unit of the title compound, [Sn(CH3)2Cl2(C14H14N2)], contains two crystallographically independent mol­ecules. In each mol­ecule, the SnIV atom is six-coordinated in a distorted octa­hedral geometry by one bidentate 2,4-di­methyl-N-(pyridin-2-yl­methyl­idene)aniline ligand, two methyl groups and two Cl atoms. In the crystal, inter­molecular C—H⋯Cl hydrogen bonds link the mol­ecules. There are π–π contacts between the pyridine rings of the ligands [centroid–centroid distance = 3.761 (4) Å]

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
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Provided by: PubMed Central

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