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(4-Chloro-2-{[(pyridin-2-ylmeth­yl)imino]­meth­yl}phenolato)iodido(methanol)zinc(II)

By Hong-Wei Huang

Abstract

The title Schiff base zinc(II) complex, [Zn(C13H10ClN2O)I(CH3OH)], was synthesized by the reaction of 5-chloro­salicyl­aldehyde, 2-amino­methyl­pyridine and zinc iodide in methanol. The ZnII atom is five-coordinated by one phenolate O atom, one imine and one pyridine N atom of the Schiff base ligand, one methanol O atom and one I atom, forming a distorted square-pyramidal geometry, with the I atom at the apical site. The dihedral angle between the benzene and pyridine rings is 22.9 (2)°. In the crystal, centrosymmetrically related mol­ecules are linked through inter­molecular O—H⋯O hydrogen bonds, forming dimers

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:3052144
Provided by: PubMed Central

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Citations

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  4. The molecular packing of the title compound, viewed along the c axis. Hydrogen atoms not involved in hydrogen bonds (dashed lines) are omitted for clarity. (4-Chloro-2-{[(pyridin-2- ylmethyl)imino]methyl}phenolato)iodido(methanol)zinc(II) Crystal data