Article thumbnail

Azido{4,4′-dibromo-2,2′-[ethane-1,2-diyl­bis(nitrilo­methanylylidene)]diphenol­ato-κ4 O,N,N′,O′}manganese(III)

By Yingxia Liu

Abstract

In the title compound, [Mn(C16H12Br2N2O2)(N3)], the MnIII ion is chelated by a tetra­dentate Schiff base ligand and coordinated by the N atom of an azide ligand in a distorted square-pyramidal arrangement. It forms phenolate-bridged out-of-plane dimers with Mn⋯Ophenolate distances of 2.667 (2) Å between pairs of inversion-related mol­ecules. In the crystal, there are offset inter-complex face-to-face π–π inter­actions [centroid–centroid distances = 3.598 (2) Å] involving one of the benzene rings of the ligands

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:3052106
Provided by: PubMed Central

To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.

Suggested articles

Citations

  1. (2008). Acta Cryst. E64, m543. metal-organic compounds m322 Yingxia Liu doi:10.1107/S1600536811004594 Acta Cryst.
  2. (1998). COLLECT. Nonius BV,
  3. Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) x y z Uiso*/Ueq Mn1
  4. (1997). Methods in Enzymology, Vol. 276, Macromolecular Crystallography, Part A, edited by