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(Methanol-κO)(methano­lato-κO)oxido[N-(2-oxidobenzyl­idene)phenyl­alaninato-κ3 O,N,O′]vanadium(V)

By Lin Bian and Lianzhi Li


In the title complex, [V(C16H13NO3)(CH3O)O(CH3OH)], the VV atom is six-coordinated by a tridentate ligand derived from the condensation of salicyl­aldehyde and l-phenyl­alanine, a vanadyl O atom, a methano­late O atom and a methanol O atom, forming a distorted octa­hedral coordination geometry. In the crystal, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds result in a two-dimensional structure parallel to (001)

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
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Provided by: PubMed Central

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  4. (1996). The two-dimensional structure of the title compound, linked by intermolecular hydrogen bonds (dashed lines). (Methanol-κO)(methanolato-κO)oxido[N-(2- oxidobenzylidene)phenylalaninato-