journal articleresearch article
oaidoi:10.1016/j.arabjc.2015.06.016

Development of one-pot three component reaction for the synthesis of N′-aryl-N-cyanoformamidines, essential precursors of formamidine pesticides family

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Publication date
31 January 2016
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The Authors. Production and hosting by Elsevier B.V.
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    Abstract

    AbstractEfficient one-pot three component reaction of aniline derivatives with cyanoamide and triethyl orthoformate at reflux in toluene affords N′-aryl-N-cyanoformamidines in high yields just by the distillation of the azeotrope toluene/ethyl alcohol. Labelled d9-Amitraz is prepared by the application of this procedure in the synthesis of formamidine pesticides family

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