Sur la thermodynamique statistique des solutions binaires

Abstract

In this paper one extends the L e n n a r d-J o n e s and D e v o n s h i r e Model to binary mixtures at temperatures far from the critical point. So it becomes possible to study the influence of the following factors on the thermodynamic functions: 1. 1. The modification with concentration of the vibration frequency of the molecules in the mean field of their neighbours; 2. 2. the volume change with concentration; Both factors give important corrections to the usual approximation of regular solutions. © 1950.SCOPUS: ar.jinfo:eu-repo/semantics/publishe