Context. X-ray spectral variability analyses of active galactic nuclei (AGN)
with moderate luminosities and redshifts typically show a softer when brighter
behaviour. Such a trend has rarely been investigated for high-luminosity AGNs
(Lbol≳1044 erg/s), nor for a wider redshift range (e.g.
0≲z≲5). Aims. We present an analysis of spectral variability
based on a large sample of 2,700 quasars, measured at several different epochs,
extracted from the fifth release of the XMM-Newton Serendipitous Source
Catalogue. Methods. We quantified the spectral variability through the
parameter β defined as the ratio between the change in the photon index
Γ and the corresponding logarithmic flux variation,
β=−ΔΓ/ΔlogFX. Results. Our analysis confirms a softer
when brighter behaviour for our sample, extending the previously found general
trend to high luminosity and redshift. We estimate an ensemble value of the
spectral variability parameter β=−0.69±0.03. We do not find dependence
of β on redshift, X-ray luminosity, black hole mass or Eddington ratio. A
subsample of radio-loud sources shows a smaller spectral variability parameter.
There is also some change with the X-ray flux, with smaller β (in
absolute value) for brighter sources. We also find significant correlations for
a small number of individual sources, indicating more negative values for some
sources
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