Densification and crystallization of Ba-exchanged zeolite A powders

Abstract

The effect of thermal treatment, Na content and mineralizer ion on the sintering process of Ba-exchanged zeolite A on the zeolite ! celsianthermal transformation are investigated. The powder samples containing different amounts of Na+ and Li+ were pressed at 30 MPa and thermallytreated at temperatures from 1000 to 1400 8C for times up to 5 h and subsequently were characterized by room temperature X-ray diffraction and byscanning electron microscopy. Increasing the Na residual content in the Ba-zeolite A samples improves the sintering process, even if the highest Nacontent appears to inhibit the zeolite! celsian transformation, since a new crystalline phase appears at the highest temperature. Moreover, theporosity of all samples thermally treated is quite high. Finally the manufacture of pressed samples allowed lower temperatures and times to be usedto obtain the transformation zeolite Ba-A ! monoclinic celsian, which suggests it is a potential method to prepare celsian low temperaturerefractory materials. At last an ANOVA analysis was carried out to identify the independent parameters from a statistical point of view