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Nucleophilic Additions to a,ß-Unsaturated Sulphones. Part III. Regiochemistry of the Reaction of (E)-Phenyl ß-Cyanovinyl Sulphone with Nitrogen, Oxygen and Carbon Nucleophiles

By F. Benedetti, S. Fabrissin, S. Pricl and A. Risaliti


The reactions of the title compound with secondary amines, alcohols, and enamines have been studied. Addition or addition-elimination at either electrophilic position is observed. Regiochemistry is a function of steric and electronic effects and of electrostatic interaction

Topics: enamine, sulfone
Year: 1987
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