Nanofiber structures are used in several technologies such as membranes, reinforced materials, textiles, catalysts,
sensors, and biomedical materials. For all these applications, it is important to know the morphology of the
assemblies, in particular their pore and fiber dimension distributions. However, the current methods used to
measure pore sizes are all experimental and indirect; furthermore, the fiber diameter distribution is usually
determined manually using a digital image of the nanofiber web. In this paper an artificial vision system is
proposed to characterize the nanofiber web by automatically measuring several properties related to the interfiber
pore distribution and to the nanofiber diameter distribution. The artificial vision system is characterized by a
two-section structure: an image processing section and a property measurement section. The image processing
section is centered on a multivariate image analysis procedure for the extraction of morphological features
from the image. The property measurement section comprises an algorithm for interfiber pore area and pore
morphology evaluation and one for fiber diameter distribution measurement that also accounts for the effect
of perspective on the lower-level fiber diameters. Because the proposed artificial vision system is completely
automatic, measurements can be taken without the need of any experimental setup and with no human
intervention. Therefore, besides being fast and accurate, measurements do not suffer from repeatability issues.
The ability of the proposed automatic system in characterizing the morphology of a thin nonwoven nanofiber
fabric is demonstrated by application to polymer nanofiber membranes obtained by electrospinning
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