New Features in the dynamics of a ferroin-catalyzed Belousov-Zhabotinsky reaction induced by a zwitterionic surfactant

Abstract

Interactions between reaction–diffusion systems and aggregated host environments are a subject of widespread interest. In this work, the behavior of the Belousov–Zhabotinsky reaction was investigated in a micellar environment formed by the zwitterionic surfactant N-tetradecyl-N,N-dimethylamine oxide (C14DMAO). The appearance of an induction period with a threshold-like dependence upon the surfactant concentration, was detected at [C14DMAO] = 5.0 10 3 mol dm 3. These new features were explained in terms of the segregation ability typical of the amphiphilic self-assembling systems. Numerical simulations were also performed to confirm the proposed mechanism