Hexanuclear [Ni6L12] metallacrown framework consisting of NiS4 square-planar and NiS5 square-pyramidal building blocks

Angamuthu, R.; Kooijman, H.; Lutz, M.; Spek, A.L.; Bouwman, E.

oai:dspace.library.uu.nl:1874/26889

Hexanuclear [Ni6L12] metallacrown framework consisting of NiS4 square-planar and NiS5 square-pyramidal building blocks

Authors: R. Angamuthu
H. Kooijman
M. Lutz
A.L. Spek
E. Bouwman
Publication date: 1 January 2007
Publisher

Abstract

The hexanuclear [Ni6L12] (2) wheel-type cluster adopts an unusual structural motif whereby four NiS4 square-planar and two NiS5 square-pyramidal units are conjoined by edge sharing; the NiS5 units resemble the Ni centre of the inactive state in the [NiFe] hydrogenase

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Utrecht University Repository

oai:dspace.library.uu.nl:1874/...

Last time updated on 14/06/2016

This paper was published in Utrecht University Repository.

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