Skip to main content
Article thumbnail
Location of Repository

Base-catalysed disproportionation and addition reactions of hexaalkylditins

By E.J. Bulten and H.A. Budding

Abstract

Under polar conditions asymmetric hexaalkylditins, R3SnSnR′3, disproportionate rapidly at room temperature to give the symmetrical ditins R6Sn2 and R′6Sn2. The equilibrium constants observed for a series of such reactions (R = Me; R′ = Et, Pt, Bu, i-Bu) point to a predominance of steric rather than inductive effects.\ud \ud Hexaalkyl-ditins (and -digermanes) also react readily under polar conditions with carbon---carbon triple bond systems as well as with diethyl azodicarboxylate

Topics: Scheikunde
Year: 1974
OAI identifier: oai:dspace.library.uu.nl:1874/18203
Download PDF:
Sorry, we are unable to provide the full text but you may find it at the following location(s):
  • http://dspace.library.uu.nl:80... (external link)
  • Suggested articles


    To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.