Skip to main content
Article thumbnail
Location of Repository

Determination of potential energy surfaces for Ar-HCl and Kr-HCl from rotational line broadening data

By J.G. Kircz, G.J.Q. van der Peyl, J. van der Elsken and D. Frenkel


Using recent rotational linebroadening data at different temperatures of HCl–Ar and HCl–Kr mixtures, an attempt is made to determine anisotropic intermolecular potential surfaces for both systems. The parameters characterizing the anisotropic part of the potential were determined from numerical fitting of computed linebroadening cross sections using the model of Smith, Giraud, and Cooper. The potential for HCl–Ar obtained that way is found to be rather different from potential surfaces that have been put forward in the literature. A comparison between the different potentials is made. In the HCl–Kr case no other ''experimental'' potential surfaces are available for comparison

Topics: Geneeskunde
Year: 1978
OAI identifier:
Download PDF:
Sorry, we are unable to provide the full text but you may find it at the following location(s):
  • (external link)
  • Suggested articles

    To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.