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Synthesis and characterization of two isomers of decacarbonyl(1,4-dialkyl-1,4-diaza-1,3-butadiene)triosmium: Os3(CO)10(R-DAB). Fluxional behaviour of Os3(CO)10(i-Pr-DAB(4e)). Molecular Structures of the 48e cluster Os3(CO)10(i-PrDAB (4e)) and of the 50e cluster Os3(CO)10(c-Pr-DAB(6e)) containing a 4e donor s,s-N,N'- and a 6e s-N,m2-N',h2-C=N' bonded R-DAB ligand respectively

By G. van Koten, R. Zoet, J.T.B.H. Jastrzebski, T. Mahabiersing, K. Vrieze, D. Heijdenrijk and C.H. Stam
Topics: Scheikunde
Year: 1988
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