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A new bile acid-derived lariat-ether: design, synthesis and cation binding properties

By P. Babu and Uday Maitra

Abstract

A new chola lariat ether (1, a 21-crown-6) was constructed fromreadily available precursors. The association constant of compound 1 with alkali metal picrates was measured using Cram's extraction protocol. Evidence is presented for the involvement of the 3-methoxy group for the complexation. Energy minimised structures show that the A-ring gets slightly distorted upon metal ion binding

Topics: QD Chemistry
Publisher: 'Springer Science and Business Media LLC'
Year: 2003
DOI identifier: 10.1007/BF02708251
OAI identifier: oai:repository.ias.ac.in:21220

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