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Hexakis(dimethyl sulfoxide-κO)calcium μ6-oxido-dodecakis-μ2-oxido-hexaoxidohexatungstate(VI)

By Jinfang Zhang

Abstract

In the title compound, [Ca(C2H6OS)6][W6O19], the cation and anion both have a crystallographically imposed centre of symmetry. The CaII atom in the cation is coordinated by six O atoms from six dimethyl sulfoxide ligands in a distorted octahedral geometry. The [W6O19]2− isopolyanion possesses the well-known Lindqvist structure in which each WVI atom is coordinated by four μ2-O, one terminal O and one μ6-O atom

Topics: Chemistry, QD1-999
Publisher: International Union of Crystallography
Year: 2012
DOI identifier: 10.1107/S1600536812018338
OAI identifier: oai:doaj.org/article:41472d2b64164a7686e10b1bc7af47fd
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