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Exceptionally active single-site nanocluster multifunctional catalysts for cascade reactions

By John M. Thomas, Robert Raja, Pratibha L. Gai, Henrik Grönbeck and Juan C. Hernández-Garrido


Cluster's last stand: Metal nanoparticles, which are well known for their catalytic properties, contain 103-106 atoms in each particle, giving rise to a continuous band of electronic energy levels. As a result, they are very different electronically from metal nanoclusters composed of aggregates of approximately 3-20 atoms. Such nanoclusters themselves exhibit remarkable catalytic performances in hydrogenation and ammoxidation cascade reactions

Topics: TA
Year: 2010
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Provided by: e-Prints Soton
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