Skip to main content
Article thumbnail
Location of Repository

Cyclic C-F-Metal Containig Species. Solid State and Computational Examples

By Hugo, De México, Maribel Arroyo Carranza and Hugo Torrens Miquel

Abstract

Abstract. This article examines the results of research published between 2000 and 2012, which found experimental evidence of cyclic species containing the fragment carbon-fluorine-transition metal. 25 Examples (numbered throughout this paper) with 20 different metals and a wide variety of chemical environments have been gathered. A similar analysis brings together almost 40 transitional states and intermediates resulting from theoretical work studying the transition metal mediated carbon-fluorine bond activation. Among other aspects, this review is useful to recognize the specific characteristics which determine whether the C-F activation process is carried out through a concerted process, a mechanism assisted by auxiliary ligands or by free radicals

Topics: Key words, Carbon, fluorine, bond activation, structure, theory
Year: 2012
OAI identifier: oai:CiteSeerX.psu:10.1.1.352.9827
Provided by: CiteSeerX
Download PDF:
Sorry, we are unable to provide the full text but you may find it at the following location(s):
  • http://citeseerx.ist.psu.edu/v... (external link)
  • http://www.jmcs.org.mx/PDFS/V5... (external link)
  • Suggested articles


    To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.