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Catalytic Decomposition of Potassium Monopersulfate. The Kinetics

By Olga Gimeno, Javier Rivas, Maria Carbajo and Teresa Borralho


Abstract—Potassium monopersulfate has been decomposed in aqueous solution in the presence of Co(II). The process has been simulated by means of a mechanism based on elementary reactions. Rate constants have been taken from literature reports or, alternatively, assimilated to analogous reactions occurring in Fenton´s chemistry. Several operating conditions have been successfully applied. Keywords—Monopersulfate, Oxone®, Sulfate radicals, Water treatment

Year: 2011
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