Context. The reactive HnO+ ions (OH+, H2O+ and H3O+) are widespread in the interstellar medium and act as precursors to the H2O
molecule. While HnO+ absorption is seen on many Galactic lines of sight, active galactic nuclei often show the lines in emission.
Aims. This paper shows the first example of a Galactic source of HnO+ line emission: the Orion Bar, a bright nearby photon-dominated
region (PDR).
Methods. We present line profiles and maps of OH+ line emission toward the Orion Bar, and upper limits to H2O+ and H3O+ lines.
We analyze these HIFI data with non-LTE radiative transfer and PDR chemical models, using newly calculated inelastic collision data
for the e-OH+ system.
Results. Line emission is detected over ∼1′ (0.12 pc), tracing the Bar itself as well as a perpendicular feature identified as the
Southern tip of the Orion Ridge, which borders the Orion Nebula on its Western side. The line width of ≈4 kms−1 suggests an
origin of the OH+ emission close to the PDR surface, at a depth of AV ∼0.3–0.5 into the cloud where most hydrogen is in atomic
form. Models with collisional and radiative excitation of OH+ require unrealistically high column densities to match the observed
line intensity, indicating that the formation of OH+ in the Bar is rapid enough to influence its excitation. Our best-fit OH+ column
density of ∼1.0×1014 cm−2 is similar to that in previous absorption line studies, while our limits on the ratios of OH+/H2O+ ( >
∼ 40) and
OH+/H3O+ ( >
∼ 15) are somewhat higher than seen before.
Conclusions. The column density of OH+ is consistent with estimates from a thermo-chemical model for parameters applicable
to the Orion Bar, given the current uncertainties in the local gas pressure and the spectral shape of the ionizing radiation field.
The unusually high OH+/H2O+ and OH+/H3O+ ratios are probably due to the high UV radiation field and electron density in this
object. Photodissociation and electron recombination are more effective destroyers of OH+ than the reaction with H2, which limits
the production of H2O+. The appearance of the OH+ lines in emission is the result of the high density of electrons and H atoms
in the Orion Bar, since for these species, inelastic collisions with OH+ are faster than reactive ones. In addition, chemical pumping,
far-infrared pumping by local dust, and near-UV pumping by Trapezium starlight contribute to the OH+ excitation. Similar conditions
may apply to extragalactic nuclei where HnO+ lines are seen in emission.
Key words. ISM: molecules – astrochemistry
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