Rhodium(III)-Catalyzed Acylation of C(sp(3))-H Bonds with Cyclopropenones

Abstract

Rh(III)-catalyzed activation and acylation of sp(3) C-H bonds has been realized with diarylcyclopropenone as an acylating reagent. Both benzylic C-H in 8-methylquinolines and unactivated C-H in 2-alkylpyridines are applicable in this C-H acylation reaction, providing enones in good yields under redox-neutral conditions

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Institutional Repository of Dalian Institute of Chemical Physics, CAS

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Last time updated on 30/03/2018

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