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Stereoselective alkyne semihydrogenations with an air-stable copper(I) catalyst

By Niklas O. Thiel and Johannes F. Teichert

Abstract

An air-stable and preactivated copper(I) hydroxide/N-heteroyclic carbene (NHC) complex for alkyne semihydrogenations is reported. Next to an enhanced practicability of the process, the resulting alkenes are obtained with high Z-selectivities and no overreduction to the corresponding alkanes

Topics: 540 Chemie und zugeordnete Wissenschaften
Year: 2016
DOI identifier: 10.1039/c6ob02271e
OAI identifier: oai:depositonce.tu-berlin.de:11303/6888
Provided by: DepositOnce
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