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Bis(2,2′-bipyridine)(2-hydroxy-2,2-diphenylacetato)copper(II) nitrate dihydrate

By Xuan Xu, Shao-Wei Mai, Chun Zheng, Xiao-Jun Wang and Yi-Fan Luo

Abstract

In the title complex, [Cu(C14H11O3)(C10H8N2)2]NO3·2H2O, the CuII atom is coordinated by four N atoms from two 2,2′-bipyridine ligands and two O atoms from one benzilate ligand in a distorted octahedral geometry. A supramolecular network is formed via intermolecular O—H...O and C—H...O hydrogen-bonding interactions. π–π stacking interactions between neighboring pyridine rings are also present, the centroid—centroid distance being 3.808 (2) Å

Topics: Chemistry, QD1-999, Science, Q, DOAJ:Chemistry (General), DOAJ:Chemistry
Publisher: International Union of Crystallography
Year: 2010
DOI identifier: 10.1107/S1600536810035555
OAI identifier: oai:doaj.org/article:0916df90c5c644a4ae418bf899b7f849
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