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Dichlorido(10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene)cadmium(II) hemihydrate

By Chun-Xiang Li, Xiu-Ying Li, Chun-Bo Liu, Yong-Sheng Yan and Guang-Bo Che

Abstract

In the title compound, [CdCl2(C18H14N4)2]·0.5H2O, the Cd atom assumes a distorted octahedral trans-CdCl2N4 geometry arising from its coordination by two N,N′-bidentate 10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene (TBBT) molecules and two chloride ions. In the crystal, π–π aromatic stacking interactions between adjacent TTBT rings are seen, with a centroid–centroid distance of 3.604 (3) Å. An O—H...Cl hydrogen bond between the half-occupied water molecule and one chloride ion also occurs

Topics: Chemistry, QD1-999, Science, Q, DOAJ:Chemistry (General), DOAJ:Chemistry
Publisher: International Union of Crystallography
Year: 2009
DOI identifier: 10.1107/S1600536808041305
OAI identifier: oai:doaj.org/article:09e03183ee4f419abf4749bcb46cd53b
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