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4-Chloro-3-fluoro-2-methylaniline–pyrrolidine-2,5-dione (1/1)

By David J. Watkin, Adel Moussa, Patrick McGarry and Benjamin A. Mayes


Chlorination of 3-fluoro-2-methylaniline with N-chlorosuccinimide gave one major regioisomer whose structure was determined by X-ray crystallography. The product was found to have cocrystallized with succinimide, giving the title compound, C7H7ClFN·C4H5NO2. The crystal structure is stabilized by N—H...O hydrogen-bonding and À–À stacking interactions with a centroid–centroid distance of 3.4501 (8) Å

Topics: Chemistry, QD1-999, Science, Q, DOAJ:Chemistry (General), DOAJ:Chemistry
Publisher: International Union of Crystallography
Year: 2008
DOI identifier: 10.1107/S1600536808018795
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