Skip to main content
Article thumbnail
Location of Repository

Hexaaquacobalt(II) bis{[N-(4-methoxy-2-oxidobenzylidene)glycylglycinato]nickel(II)} hexahydrate

By Wenlong Liu, Limin Yuan, Yao Lu and Jiaxun Jiang

Abstract

In the title compound, [Co(H2O)6][Ni(C12H11N2O5)]2·6H2O, the NiII atom has a nearly square-planar coordination with two N and two O atoms of the N-(4-methoxy-2-oxidobenzylidene)glycylglycinate Schiff base ligand (L3−). The CoII atom sits on an inversion center and is coordinated to six aqua ligands in a slightly distorted octahedral geometry. The [Co(H2O)6]2+ cations and [NiL]− anions form columns along the a axis by O—H...O hydrogen bonds. Additional hydrogen bonds between the uncoordinated and coordinated water molecules help to consolidate the crystal packing

Topics: Chemistry, QD1-999, Science, Q, DOAJ:Chemistry (General), DOAJ:Chemistry
Publisher: International Union of Crystallography
Year: 2009
DOI identifier: 10.1107/S1600536809026750
OAI identifier: oai:doaj.org/article:3b430fa050c148299d1a5ab970a30cae
Journal:
Download PDF:
Sorry, we are unable to provide the full text but you may find it at the following location(s):
  • https://doaj.org/toc/1600-5368 (external link)
  • http://scripts.iucr.org/cgi-bi... (external link)
  • https://doaj.org/article/3b430... (external link)
  • Suggested articles


    To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.