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A segunda lei da termodinâmica

By Martina Costa Reis and Adalberto Bono Maurizio Sacchi Bassi

Abstract

Considering intrinsic characteristics of the system exclusively, both statistical and information theory interpretations of the second law are used to provide more comprehensive meanings for the concepts of entropy, temperature, and Helmholtz and Gibbs energies. The coherence of Clausius inequality to these concepts is emphasized. The aim of this work is to re-discuss the second law of thermodynamics in accordance to homogeneous processes thermodynamics, a temporal science which is the very special oversimplification of continuum mechanics for spatially constant intensive properties

Topics: entropy, temperature, Clausius inequality, Chemistry, QD1-999, Science, Q
Publisher: Sociedade Brasileira de Química
Year: 2012
DOI identifier: 10.1590/S0100-40422012000500035
OAI identifier: oai:doaj.org/article:39af8227c5f2492caa5b0ce8de262741
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