Location of Repository

Aquabis(2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olato)zinc(II) monohydrate

By Yu-Feng Wei, Zhong-Shu Li, Huai-Hong Zhang and Yi-Hong Wang

Abstract

The crystal structure of the title compound, [Zn(C9H7N2O2)2(H2O)]·H2O, involves discrete mononuclear complex molecules. The special positions on the rotation twofold axis are occupied by ZnII and O atoms of the coordinated and uncoordinated water molecules. The coordination around the ZnII atom can be described as transitional from trigonal-bipyramidal to square-pyramidal. The two chelating 2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olate ligands and the coordinated water molecule form the Zn coordination. O—H...O hydrogen bonds between the coordinated water molecule and the ligand and between the uncoordinated water molecule and the ligand dominate the crystal packing

Topics: Chemistry, QD1-999, Science, Q, DOAJ:Chemistry (General), DOAJ:Chemistry
Publisher: International Union of Crystallography
Year: 2009
DOI identifier: 10.1107/S1600536808039615
OAI identifier: oai:doaj.org/article:232114a2babf48d6acc3d9e458b8c454
Journal:
Download PDF:
Sorry, we are unable to provide the full text but you may find it at the following location(s):
  • https://doaj.org/toc/1600-5368 (external link)
  • http://scripts.iucr.org/cgi-bi... (external link)
  • https://doaj.org/article/23211... (external link)
  • Suggested articles


    To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.