École Polytechnique Fédérale de Lausanne

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    Through thickness air permeability of prepregs during cure

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    An experimental method based on a falling pressure measurement is proposed to evaluate the through thickness air permeability of prepregs during cure, with two set-up variants. One concerns the measurement of the inherent air permeability and the other applies to processing conditions, implying the use of consumables and vacuum-bag. The methods were successfully tested and fulfil the criterions used in soil science for the evaluation of the air permeability. Prepreg permeability to air during cure varies between 10−17 m2 and 10−19 m2 and is found to depend on the evolution of the resin viscosity, which shifts from an initially immobile phase to a mobile one and back to an immobile phase.LT

    Template Nanowires for Spintronics Applications: Nanomagnet Microwave Resonators Functioning in Zero Applied Magnetic Field

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    Low-cost spintronic devices functioning in zero applied magnetic field are required for bringing the idea of spin-based electronics into the real-world industrial applications. Here we present first microwave measurements performed on nanomagnet devices fabricated by electrodeposition inside porous membranes. In the paper, we discuss in details a microwave resonator consisting of three nanomagnets, which functions in zero external magnetic field. By applying a microwave signal at a particular frequency, the magnetization of the middle nanomagnet experiences the ferromagnetic resonance (FMR), and the device outputs a measurable direct current (spin-torque diode effect). Alternatively, the nanodevice can be used as a microwave oscillator functioning in zero field. To test the resonators at microwave frequencies, we developed a simple measurement setup.LPM

    Synthesis and characterization of ether-derivatized aminophosphines and their application in C-C coupling reactions

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    Four new bis(phosphino)amine ligands (Ph2P)2N-C6H3-R, where R = 3,5-OMe (1), 2,5-OMe (2), 2,4-OMe (3) or 3,4-OMe (4), were prepd. via aminolysis of the corresponding dimethoxyanilines with 2 equiv. of diphenylphosphine chloride in the presence of tri-Et amine. Oxidn. of these ligands with aq. H2O2, elemental S8 or Se powder afforded the corresponding chalcogen oxides 1a-4a, sulfides 1b-4b and selenides 1c-4c in good yields. Reaction of 1-4 with [MCl2(cod)] (M = Pt, Pd; cod = cycloocta-1,5-diene) in equimolar ratios afforded cis-[MCl2{(Ph2P)2N-C6H3-R}] (M = Pt; R = 3,5-OMe 1d, R = 2,5-OMe 2d, R = 2,4-OMe 3d, and R = 3,4-OMe 4d. M = Pd; R = 3,5-OMe 1e, R = 2,5-OMe 2e, R = 2,4-OMe 3e, and R = 3,4-OMe 4e). Similarly, reaction of [Cu(CH3CN)4]PF6 with the 1-4 in 1:2 ratio gave [Cu{(Ph2P)2N-C6H3-R}2]PF6 (R = 3,5-OMe 1f, 2,5-OMe 2f, 2,4-OMe 3f and 3,4-OMe 4f). All new compds. were fully characterized by spectroscopy and elemental anal. and the mol. structures of seven representative compds. were detd. by single-crystal X-ray crystallog. In addn., the palladium complexes were investigated as pre-catalysts in C-C coupling reactions.LCO

    Deceleration of neutral molecules in macroscopic traveling traps

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    A decelerator is presented where polar neutral molecules are guided and decelerated using the principle of traveling electric potential wells, such that molecules are confined in stable three-dimensional traps throughout. We compare this decelerator with that of Scharfenberg et al. [Phys. Rev. A 79, 023410 (2009)] and we show that the current decelerator provides a substantially larger phase-space acceptance, even at higher acceleration. The mode of operation is described and experimentally demonstrated by guiding and decelerating CO molecules.GR-OS

    Characterization of glycoprotein E C-End of West Nile virus and evaluation of its interaction force with alpha V beta 3 integrin as putative cellular receptor

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    Recombinant polypeptide containing the 260-466 amino acid sequence of West Nile virus (WNV) strain LEIV-Vlg99-27889-human glycoprotein E (gpE, E260-466) was constructed. Immunochemical similarity between the E260-466 and gpE of WNV was proven by enzyme immunoassay (EIA), immunoblot, competitive EIA, hemagglutination inhibition, and neutralization tests using polyclonal and monoclonal antibodies against the viral gpE and recombinant E260-466. Polypeptide E260-466 induced formation of virus neutralizing and cross-reactive antibodies that were interactive with various epitopes of this recombinant protein. It is shown by evaluation of the interaction of E260-466 with one of the proposed cell receptors of WNV that average E260-466-alpha V beta 3 integrin-specific interaction force measured using atomic force spectroscopy was 80 and 140 pN for single and double interactions, correspondingly. Taken together with previously described interaction between laminin-binding protein (LBP) and WNV gpE domain II, it is proposed that WNV gpE can interact specifically with two cellular proteins (LBP and alpha V beta 3 integrin) during virus entry.LPM

    Learning in the Face of Power

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    Formation des Adultes et Epistémologie des Sciences Humaines [Adult Education and the Epistemology of the Human Sciences]

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    MIRtitre Anglais: Adult Education and the Epistemology of the Human Sciences

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