10,363 research outputs found
Kinetics of Phase Separation in Thin Films: Simulations for the Diffusive Case
We study the diffusion-driven kinetics of phase separation of a symmetric
binary mixture (AB), confined in a thin-film geometry between two parallel
walls. We consider cases where (a) both walls preferentially attract the same
component (A), and (b) one wall attracts A and the other wall attracts B (with
the same strength). We focus on the interplay of phase separation and wetting
at the walls, which is referred to as {\it surface-directed spinodal
decomposition} (SDSD). The formation of SDSD waves at the two surfaces, with
wave-vectors oriented perpendicular to them, often results in a metastable
layered state (also referred to as ``stratified morphology''). This state is
reminiscent of the situation where the thin film is still in the one-phase
region but the surfaces are completely wet, and hence coated with thick wetting
layers. This metastable state decays by spinodal fluctuations and crosses over
to an asymptotic growth regime characterized by the lateral coarsening of
pancake-like domains. These pancakes may or may not be coated by precursors of
wetting layers. We use Langevin simulations to study this crossover and the
growth kinetics in the asymptotic coarsening regime.Comment: 39 pages, 19 figures, submitted to Phys.Rev.
A New Monte Carlo Method and Its Implications for Generalized Cluster Algorithms
We describe a novel switching algorithm based on a ``reverse'' Monte Carlo
method, in which the potential is stochastically modified before the system
configuration is moved. This new algorithm facilitates a generalized
formulation of cluster-type Monte Carlo methods, and the generalization makes
it possible to derive cluster algorithms for systems with both discrete and
continuous degrees of freedom. The roughening transition in the sine-Gordon
model has been studied with this method, and high-accuracy simulations for
system sizes up to were carried out to examine the logarithmic
divergence of the surface roughness above the transition temperature, revealing
clear evidence for universal scaling of the Kosterlitz-Thouless type.Comment: 4 pages, 2 figures. Phys. Rev. Lett. (in press
Far-from-equilibrium growth of thin films in a temperature gradient
The irreversible growth of thin films under far-from-equilibrium conditions
is studied in dimensional strip geometries. Across one of the
transverse directions, a temperature gradient is applied by thermal baths at
fixed temperatures between and , where and
is the critical temperature of the system in contact with
an homogeneous thermal bath. By using standard finite-size scaling methods, we
characterized a continuous order-disorder phase transition driven by the
thermal bath gradient with critical temperature and critical
exponents , , and , which belong
to a different universality class from that of films grown in an homogeneous
bath. Furthermore, the effects of the temperature gradient are analyzed by
means of a bond model that captures the growth dynamics. The interplay of
geometry and thermal bath asymmetries leads to growth bond flux asymmetries and
the onset of transverse ordering effects that explain qualitatively the shift
in the critical temperature.Comment: 4 pages, 4 figures. arXiv admin note: substantial text overlap with
arXiv:1207.253
Domain Growth in Ising Systems with Quenched Disorder
We present results from extensive Monte Carlo (MC) simulations of domain
growth in ferromagnets and binary mixtures with quenched disorder. These are
modeled by the "random-bond Ising model" and the "dilute Ising model" with
either nonconserved (Glauber) spin-flip kinetics or conserved (Kawasaki)
spin-exchange kinetics. In all cases, our MC results are consistent with
power-law growth with an exponent which depends on the
quench temperature and the disorder amplitude . Such exponents
arise naturally when the coarsening domains are trapped by energy barriers
which grow logarithmically with the domain size. Our MC results show excellent
agreement with the predicted dependence of .Comment: 11 pages, 15 figure
Orientational correlations and the effect of spatial gradients in the equilibrium steady state of hard rods in 2D : A study using deposition-evaporation kinetics
Deposition and evaporation of infinitely thin hard rods (needles) is studied
in two dimensions using Monte Carlo simulations. The ratio of deposition to
evaporation rates controls the equilibrium density of rods, and increasing it
leads to an entropy-driven transition to a nematic phase in which both static
and dynamical orientational correlation functions decay as power laws, with
exponents varying continuously with deposition-evaporation rate ratio. Our
results for the onset of the power-law phase agree with those for a conserved
number of rods. At a coarse-grained level, the dynamics of the non-conserved
angle field is described by the Edwards-Wilkinson equation. Predicted relations
between the exponents of the quadrupolar and octupolar correlation functions
are borne out by our numerical results. We explore the effects of spatial
inhomogeneity in the deposition-evaporation ratio by simulations, entropy-based
arguments and a study of the new terms introduced in the free energy. The
primary effect is that needles tend to align along the local spatial gradient
of the ratio. A uniform gradient thus induces a uniformly aligned state, as
does a gradient which varies randomly in magnitude and sign, but acts only in
one direction. Random variations of deposition-evaporation rates in both
directions induce frustration, resulting in a state with glassy
characteristics.Comment: modified version, Accepted for publication in Physical Review
Critical behavior of colloid-polymer mixtures in random porous media
We show that the critical behavior of a colloid-polymer mixture inside a
random porous matrix of quenched hard spheres belongs to the universality class
of the random-field Ising model. We also demonstrate that random-field effects
in colloid-polymer mixtures are surprisingly strong. This makes these systems
attractive candidates to study random-field behavior experimentally.Comment: 4 pages, 3 figures, to appear in Phys. Rev. Let
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