Recrystallization of epitaxial GaN under indentation

We report recrystallization of epitaxial (epi-) GaN(0001) film under indentation.Hardness value is measured close to 10 GPa, using a Berkovich indenter. Pop-in burst in the loading line indicates nucleation of dislocations setting in plastic motion of lattice atoms under stress field for the recrystallization process. Micro-Raman studies are used to identify the recrystallization process. Raman area mapping indicates the crystallized region. Phonon mode corresponding to E2(high) close to 570 cm-1 in the as-grown epi-GaN is redshifted to stress free value close to 567 cm-1 in the indented region. Evolution of A1(TO) and E1(TO) phonon modes are also reported to signify the recrystallization process.Comment: 10 pages, 3 figures

A continuum model accounting for the effect of the initial and evolving microstructure on the evolution of dynamic recrystallization

Laser assisted forming is a process which is increasingly being adopted by the industry. Application of heat by a laser to austenitic stainless steel (ASS) sheet provides local control over formability and strength of the material. The hot forming behavior of ASS is characterized by significant dynamic recovery and dynamic recrystallization. These two processes lead to a softening stress-strain response and have a significant impact on the microstructure of the material. Most of the research performed on hot forming of ASS focuses on dynamic recrystallization and then specifically on the behavior of the annealed state, consisting of relatively large equiaxed austenite grains. However, in industry it is common to use cold rolled ASS sheet which is a mixture of austenite and martensite. Application of a laser heat treatment to the cold rolled grades of ASS induces a socalled ‘reverse’ transformation of martensite to austenite which, depending on the exact time-temperature combinations, leads to an austenite grain size in the range of nanoto micrometer. It is known from experiments that the effect of initial grain size on dynamic recrystallization is significant, especially on the initial stages of recrystallization. Therefore any continuum model capable of describing hot forming of cold rolled ASS should include the effect of the initial grain size. In this work a physically based continuum model for dynamic recrystallization is presented which accounts for the effect of the initial and evolving grain size on the evolution of dynamic recrystallization. It is shown that the initial grain size can be accounted for by incorporating its effect on the availability of preferred nucleation sites, i.e. grain edges. The new model is compared to experimental results and it is shown that the model correctly predicts accelerated recrystallization with decrease in grain size and that there is a weak dependence of the dynamically recrystallized grain size on the initial grain size. Furthermore predicted recrystallized grain sizes are in good agreement with the experimentally measured values

Direct observation via in situ heated stage EBSD analysis of recrystallization of phosphorous deoxidised copper in unstrained and strained conditions

Recrystallization of phosphorous deoxidised copper used for strength critical applications at elevated temperatures was investigated by means of in situ heated stage EBSD analysis using a Gatan Murano heated stage mounted within a Carl Zeiss Sigma FEGSEM electron microscope. The influence of applied strain as the result of deformation within a Nakajima test as an analogue for industrial forming on the recrystallization temperature was investigated, the impact of increased heating rates on microstructural evolution was also investigated. Inverse pole figure plots combined with regions of reduction in local misorientations and variations in geometrically necessary dislocations were used to establish the point of recrystallization and the recrystallized fraction of the material. Recrystallization was observed to occur at temperatures as low as 130 °C in highly strained samples compared to around 300 °C within the annealed samples dependent upon heating rate. Increased heating rates were observed to produce a finer final grain structure but had little effect on presence of 60° grain twins, which was influenced more by initial material condition

Characterization of the austenite recrystallization by comparing double deformation and stress relaxation tests

A high amount of deformation below the non-recrystallization temperature (T-nr) is a common industrial practice to achieve a good combination of toughness and strength in microalloyed steels. To combine the industrially relevant optimum combination of high productivity and product quality, an accurate knowledge of T-nr and the recrystallization kinetics is required. Although a lot of literature data is available on the recrystallization behaviour of microalloyed steels, correlations are often difficult to be made due to the effect of different experimental setups, types of analysis and test schedules that are used to obtain this data. Although this would significantly improve the knowledge about these steels, so far, no systematic comparison has been presented in literature to correlate the different techniques and methods. In this study, different hot rolling simulation techniques, testing schedules and types of analysis were used to determine the recrystallization kinetics of a microalloyed steel. On the one hand, good agreement was found between the results from different test equipment for the double deformations tests. On the other hand, stress relaxation tests showed accelerated kinetics and appeared to be less effective

Control of the Austenite recrystallization in Niobium Microalloyed steels

The use of heavy gauge steel sheets for structural applications very often requires a combination of high yield strength and adequate toughness. The most cost effective way to realize a high yield strength and a high ductility in a low alloyed steel is grain refinement. In industrial practice, this refinement is realized by controlled processing. This process consists of controlling the slab reheating temperature, applying a large amount of hot deformation below the nonrecrystallization temperature (T-nr) and accelerated cooling. A better knowledge of T-nr could optimize the process and the best mechanical properties could be reached against the lowest cost. T-nr can be raised by the addition of microalloying elements such as Nb. Nb can retard the static recrystallization of austenite at low temperatures either by solute drag or by precipitation pinning. In this study, the recrystallization behavior of five Nb-microalloyed model alloys with various Nb contents, was evaluated by double hit compression tests. Further, the precipitation state of the materials was investigated experimentally by Inductively Couples Mass Spectroscopy and X-ray Diffraction. The construction of recrystallization-time-temperature diagrams and precipitation-time-temperature diagrams showed that both mechanisms, i.e. recrystallization and precipitation, strongly influence each other

Cellular monotectic model solidification

Succinonitrile (sn) was purified to a superior level using a fractional recrystallization method. The melting point of the best twice recrystallized sn was not raised by following with double distillation. This was tested using differential scanning calorimetry. The peak shape on melting also proved that double distillation after double recrystallization did not improve the quality. Stability and phase diagrams for succinonitrile and glycerol are presented

Dynamic recrystallization mechanisms and twining evolution during hot deformation of Inconel 718

The hot deformation behavior of an IN718 superalloy was studied by isothermal compression tests under the deformation temperature range of 950–1100 °C and strain rate range of 0.001–1 s-1 up to true strains of 0.05, 0.2, 0.4 and 0.7. Electron backscattered diffraction (EBSD) technique was employed to investigate systematically the effects of strain, strain rate and deformation temperature on the subgrain structures, local and cumulative misorientations and twinning phenomena. The results showed that the occurrence of dynamic recrystallization (DRX) is promoted by increasing strain and deformation temperature and decreasing strain rate. The microstructural changes showed that discontinuous dynamic recrystallization (DDRX), characterized by grain boundary bulging, is the dominant nucleation mechanism in the early stages of deformation in which DRX nucleation occurs by twining behind the bulged areas. Twin boundaries of nuclei lost their ¿3 character with further deformation. However, many simple and multiple twins can be also regenerated during the growth of grains. The results showed that continuous dynamic recrystallization (CDRX) is promoted at higher strains and large strain rates, and lower temperatures, indicating that under certain conditions both DDRX and CDRX can occur simultaneously during the hot deformation of IN718.Peer ReviewedPostprint (author's final draft