Quasi-Freestanding Multilayer Graphene Films on the Carbon Face of SiC

The electronic band structure of as-grown and doped graphene grown on the carbon face of SiC is studied by high-resolution angle-resolved photoemission spectroscopy, where we observe both rotations between adjacent layers and AB-stacking. The band structure of quasi-freestanding AB- bilayers is directly compared with bilayer graphene grown on the Si-face of SiC to study the impact of the substrate on the electronic properties of epitaxial graphene. Our results show that the C-face films are nearly freestanding from an electronic point of view, due to the rotations between graphene layers.Comment: http://link.aps.org/doi/10.1103/PhysRevB.81.24141

Metrics that matter for assessing the ocean biological carbon pump

© The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Buesseler, K. O., Boyd, P. W., Black, E. E., & Siegel, D. A. Metrics that matter for assessing the ocean biological carbon pump. Proceedings of the National Academy of Sciences of the United States of America, (2020): 201918114, doi: 10.1073/pnas.1918114117.The biological carbon pump (BCP) comprises wide-ranging processes that set carbon supply, consumption, and storage in the oceans’ interior. It is becoming increasingly evident that small changes in the efficiency of the BCP can significantly alter ocean carbon sequestration and, thus, atmospheric CO2 and climate, as well as the functioning of midwater ecosystems. Earth system models, including those used by the United Nation’s Intergovernmental Panel on Climate Change, most often assess POC (particulate organic carbon) flux into the ocean interior at a fixed reference depth. The extrapolation of these fluxes to other depths, which defines the BCP efficiencies, is often executed using an idealized and empirically based flux-vs.-depth relationship, often referred to as the “Martin curve.” We use a new compilation of POC fluxes in the upper ocean to reveal very different patterns in BCP efficiencies depending upon whether the fluxes are assessed at a fixed reference depth or relative to the depth of the sunlit euphotic zone (Ez). We find that the fixed-depth approach underestimates BCP efficiencies when the Ez is shallow, and vice versa. This adjustment alters regional assessments of BCP efficiencies as well as global carbon budgets and the interpretation of prior BCP studies. With several international studies recently underway to study the ocean BCP, there are new and unique opportunities to improve our understanding of the mechanistic controls on BCP efficiencies. However, we will only be able to compare results between studies if we use a common set of Ez-based metrics.We thank the many scientists whose ideas and contributions over the years are the foundation of this paper. This includes A. Martin, who led the organization of the BIARRITZ group (now JETZON) workshop in July 2019, discussions at which helped to motivate this article. We thank D. Karl for pointing us in the right direction for this paper format at PNAS and two thoughtful reviewers who through their comments helped to improve this manuscript. Support for writing this piece is acknowledged from several sources, including the Woods Hole Oceanographic Institution’s Ocean Twilight Zone project (K.O.B.); NASA as part of the EXport Processes in the global Ocean from RemoTe Sensing (EXPORTS) program (K.O.B. and D.A.S.). E.E.B. was supported by a postdoctoral fellowship through the Ocean Frontier Institute at Dalhousie University. P.W.B. was supported by the Australian Research Council through a Laureate (FL160100131)

A light-driven, one-dimensional dimethylsulfide biogeochemical cycling model for the Sargasso Sea

Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 113 (2008): G02009, doi:10.1029/2007JG000426.We evaluate the extent to which dimethylsulfide (DMS) cycling in an open-ocean environment can be constrained and parameterized utilizing emerging evidence for the significant impacts of solar ultraviolet radiation (UVR) on the marine organic sulfur cycle. Using the Dacey et al. (1998) 1992–1994 Sargasso Sea DMS data set, in conjunction with an offline turbulent mixing model, we develop and optimize a light driven, one-dimensional DMS model for the upper 140 m. The DMS numerical model is primarily diagnostic in that it incorporates observations of bacterial, phytoplankton, physical, and optical quantities concurrently measured as part of the Bermuda Atlantic Time-series Study (BATS) and Bermuda Bio-Optical Project (BBOP) programs. With the exception of sea-to-air ventilation, each of the sulfur cycling terms is explicitly parameterized or altered by the radiation field. Overall, the model shows considerable skill in capturing the salient features of the DMS distribution, specifically the observed DMS summer paradox whereby peak summer DMS concentrations occur coincident with annual minima in phytoplankton pigment biomass and primary production. The dominant processes controlling the upper-ocean DMS concentrations are phytoplankton UVR-induced DMS release superimposed upon more surface oriented processes such as photolysis and sea-to-air ventilation. The results also demonstrate that mixing alone is not enough to parameterize DMS distributions in this environment. It is critical to directly parameterize the seasonal changes in the flux and attenuation of solar radiation in the upper water column to describe the DMS distribution with depth and allow for experimentation under a variety of climate change scenarios.This work was supported by NASA under an Earth System Science Fellowship, a WHOI Ocean and Climate Change Institute Postdoctoral scholarship, and NSF OCE-0525928

Many-body interactions in quasi-freestanding graphene

The Landau-Fermi liquid picture for quasiparticles assumes that charge carriers are dressed by many-body interactions, forming one of the fundamental theories of solids. Whether this picture still holds for a semimetal like graphene at the neutrality point, i.e., when the chemical potential coincides with the Dirac point energy, is one of the long-standing puzzles in this field. Here we present such a study in quasi-freestanding graphene by using high-resolution angle-resolved photoemission spectroscopy. We see the electron-electron and electron-phonon interactions go through substantial changes when the semimetallic regime is approached, including renormalizations due to strong electron-electron interactions with similarities to marginal Fermi liquid behavior. These findings set a new benchmark in our understanding of many-body physics in graphene and a variety of novel materials with Dirac fermions.Comment: PNAS 2011 ; published ahead of print June 27, 201