6,161 research outputs found
Quantum diffusion on a cyclic one dimensional lattice
The quantum diffusion of a particle in an initially localized state on a
cyclic lattice with N sites is studied. Diffusion and reconstruction time are
calculated. Strong differences are found for even or odd number of sites and
the limit N->infinit is studied. The predictions of the model could be tested
with micro - and nanotechnology devices.Comment: 17 pages, 5 figure
Development of a Thiol-capped Core/Shell Quantum Dot Sensor for Acetaminophen
Acetaminophen (AC) is a frequently used pharmaceutical which has been detected in water systems and is of concern due to its
potential environmental impacts. In this study, three quantum dot (QD)-ligand systems, namely L-cysteine (L-cys)-, N-acetyl-
L-cysteine (NAC)- and glutathione (GSH)-capped CdSe/ZnS quantum dots, were synthesized and tested for the fluorescence
detection of acetaminophen. Among the synthesized aqueous core/shell quantum dots, L-cys-CdSe/ZnS QDs were found to be
optimal with high sensitivity for the fluorescence detection of acetaminophen. The L-cys-CdSe/ZnS QDs were of a zinc blende
crystal structure and displayed excellent fluorescence intensity and photostability and provided a photoluminescence quantum
yield of 77 % . The fluorescence of L-cys-CdSe/ZnS QDs was enhanced by the introduction of AC enabling the development of a
fast and simple method for the detection of AC. Under optimal conditions, F-F0 was linearly proportional to the concentration of
AC from 3.0–100 nmol L–1 with limits of detection and quantification of 1.6 and 5.3 nmol L–1, respectively. Some related pharmaceutical
compounds including epinephrine hydrochloride (EP), L-ascorbic acid (AA), uric acid (UA), dopamine hydrochloride
(DA) and 4-aminophenol (4-AP) did not interfere with the sensing ofAC. The probe was also successfully applied in the determination
of AC in tap and river water matrices.The University of Pretoria, the Water
Research Commission (Grant K5/2438/1 and K5/2752) as well as
the Photonics Initiative of South Africa (Grant PISA-15-DIR-06).http://www.journals.co.za/sajchemam2019Chemistr
Current practice of preparing morphine infusions for nurse/patient-controlled analgesia in a UK paediatric hospital: healthcare professionals' views and experiences
Objective To explore the views and experiences of healthcare professionals (HCPs) regarding the preparation of morphine infusions for nurse/patient-controlled analgesia (N/PCA). Methods Three focus groups were conducted with HCPs (anaesthetists, nurses in theatres and wards) at one UK children's hospital. Focus groups were transcribed verbatim and content analysis was used to identify themes. Results A variety of approaches are used to prepare morphine infusions. A lack of appreciation of the excess volume present in morphine ampoules that nominally contain 1 or 2 mL was identified. Other sources of error were miscalculation, complexity of the multistep procedure, distractions and time pressure. Participants suggested that ‘ready-to-use’ prefilled syringes and preprogrammed syringe pumps would improve practice and minimise the risk of error. Conclusions Risks associated with the preparation of infusions for paediatric N/PCA, in particular non-appreciation of the overage (excess volume) in morphine ampoules, raise concerns about the accuracy of current practices
Does Habitat Management for Northern Bobwhites Benefit the Red Imported Fire Ant?
Red imported fire ants (Solenopsis invicta) have caused damage to agricultural, economic, and wildlife resources since their accidental introduction. Previous studies have suggested that red imported fire ant (RIFA) mound densities are positively correlated to habitats maintained through disturbance. Prescribed burning and disking are two techniques commonly used to disturb portions of the landscape to maintain early successional habitats for northern bobwhite (Colinus virginianus). We tested the hypothesis that prescribed burning and disking would increase RIFA mound densities. This study was conducted in Refugio County, Texas in the Texas Coastal Prairie on Loamy Prairie range sites. Red imported fire ant mound densities were different between years (F = 5.05, df = 2, P = 0.0148). However, burning and disking had no impact (F = 0.22, df = 2, P = 0.8044) on RIFA mound densities. Initially high RIFA mound densities in our study area coupled with the territoriality of predominantly monogyne (single-queen) colonies may have limited increases in RIFA mound density in response to treatments on these study sites
Political attitudes of the young electorate in the 2016 presidential election and parental influences on political identity formation.
We examined the political attitudes of college-aged students and the political identities of their parents to better understand the role that both parent-child political socialization and the liberal university environment play in political identity formation. We compared students explicit and implicit political attitudes and examined the relationships of these attitudes to the political identities of their parents. We also explored the uniqueness of two candidates, Bernie Sanders and Donald Trump in the 2016 Presidential election. Our results supported the existing notion of parental influences on political identity formation and revealed that the university environment may not play as large of a role in shifting first and second year university students away from political identities established at home. However, data revealed greater support for the non-traditional candidate in our left-leaning participants, suggesting that factors other than parent influence could be at play in forming the political identities of the youth
Restoring observed classical behavior of the carbon nanotube field emission enhancement factor from the electronic structure
Experimental Fowler-Nordheim plots taken from orthodoxly behaving carbon
nanotube (CNT) field electron emitters are known to be linear. This shows that,
for such emitters, there exists a characteristic field enhancement factor (FEF)
that is constant for a range of applied voltages and applied macroscopic fields
. A constant FEF of this kind can be evaluated for classical CNT
emitter models by finite-element and other methods, but (apparently contrary to
experiment) several past quantum-mechanical (QM) CNT calculations find
FEF-values that vary with . A common feature of most such
calculations is that they focus only on deriving the CNT real-charge
distributions. Here we report on calculations that use density functional
theory (DFT) to derive real-charge distributions, and then use these to
generate the related induced-charge distributions and related fields and FEFs.
We have analysed three carbon nanostructures involving CNT-like nanoprotrusions
of various lengths, and have also simulated geometrically equivalent classical
emitter models, using finite-element methods. We find that when the
DFT-generated local induced FEFs (LIFEFs) are used, the resulting values are
effectively independent of macroscopic field, and behave in the same
qualitative manner as the classical FEF-values. Further, there is fair to good
quantitative agreement between a characteristic FEF determined classically and
the equivalent characteristic LIFEF generated via DFT approaches. Although many
issues of detail remain to be explored, this appears to be a significant step
forwards in linking classical and QM theories of CNT electrostatics. It also
shows clearly that, for ideal CNTs, the known experimental constancy of the FEF
value for a range of macroscopic fields can also be found in appropriately
developed QM theory.Comment: A slightly revised version has been published - citation below -
under a title different from that originally used. The new title is:
"Restoring observed classical behavior of the carbon nanotube field emission
enhancement factor from the electronic structure
Moyal star product approach to the Bohr-Sommerfeld approximation
The Bohr-Sommerfeld approximation to the eigenvalues of a one-dimensional
quantum Hamiltonian is derived through order (i.e., including the
first correction term beyond the usual result) by means of the Moyal star
product. The Hamiltonian need only have a Weyl transform (or symbol) that is a
power series in , starting with , with a generic fixed point in
phase space. The Hamiltonian is not restricted to the kinetic-plus-potential
form. The method involves transforming the Hamiltonian to a normal form, in
which it becomes a function of the harmonic oscillator Hamiltonian.
Diagrammatic and other techniques with potential applications to other normal
form problems are presented for manipulating higher order terms in the Moyal
series.Comment: 27 pages, no figure
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