Method to Look for Imprints of Ultrahigh Energy Nuclei Sources

We propose a new method to search for heavy nuclei sources, on top of background, in the Ultra-High Energy Cosmic Ray data. We apply this method to the 69 events recently published by the Pierre Auger Collaboration and find a tail of events for which it reconstructs the source at a few degrees from the Virgo galaxy cluster. The reconstructed source is located at ~ 8.5 degrees from M87. The probability to have such a cluster of events in some random background and reconstruct the source position in any direction of the sky is about 7 x 10^(-3). The probability to reconstruct the source at less than 10 degrees from M87 in a data set already containing such a cluster of events is about 4 x 10^(-3). This may be a hint at the Virgo cluster as a bright ultra-high energy nuclei source. We investigate the ability of current and future experiments to validate or rule out this possibility, and discuss several alternative solutions which could explain the existing anisotropy in the Auger data.Comment: 12 pages (2 columns), 10 figures. Published in Physical Review

Genealogical Inquiry and Universal Moral Values

Inspired by american pragmatism and Hans Joas' proposal of an affirmative genealogy, I argue in this paper that a genealogical inquiry (both on the biografical and on the historical level) can explain what motivates individuals to moral agency better than Kantian moral philosophy, without renouncing an historically-informed conception of universal moral values

The Bargiolina, a striking historical stone from Monte Bracco (Piedmont, NW Italy) and a possible source of industrial minerals

The Bargiolina quartzite from Monte Bracco (western Alps, northern Italy) represents one of the most important historical ornamental stones of the Piedmont region. Known and used since the prehistoric age as substituting material for chert, it was celebrated by Leonardo da Vinci, and exploited at least since the XIII century, peaking in the XX century. It was extensively used in the construction of basilicas and noble palaces by famous architects of Piedmontese Baroque, for internal and external stone cladding. There are four main commercial and chromatic varieties, and the main technical feature is the regular schistosity, to obtain very thin natural split slabs. The different varieties have a homogeneous mineralogical composition and microstructure: A fine and homeoblastic grain size, and a granular—lepidoblastic texture, with regularly spaced schistose domains. The main rock-forming minerals are quartz, phengite, small amounts of K-feldspar and traces of plagioclase and chlorite. The yield rate of quarries is about 20%, and the poor exploitation planning of the past led to only partly exploited quarry benches, with a very poor residual yield. The large amount of quartz-rich quarry waste and the presence of kaolin-rich gneisses suggests the potential for novel applications in the field of industrial minerals

Probing the Structure of Jet Driven Core-Collapse Supernova and Long Gamma Ray Burst Progenitors with High Energy Neutrinos

Times of arrival of high energy neutrinos encode information about their sources. We demonstrate that the energy-dependence of the onset time of neutrino emission in advancing relativistic jets can be used to extract important information about the supernova/gamma-ray burst progenitor structure. We examine this energy and time dependence for different supernova and gamma-ray burst progenitors, including red and blue supergiants, helium cores, Wolf-Rayet stars, and chemically homogeneous stars, with a variety of masses and metallicities. For choked jets, we calculate the cutoff of observable neutrino energies depending on the radius at which the jet is stalled. Further, we exhibit how such energy and time dependence may be used to identify and differentiate between progenitors, with as few as one or two observed events, under favorable conditions

A two-rigid block model for sliding gravity retaining walls

This paper presents a new two rigid block model for sliding gravity retaining walls. Some conceptual limitations of a direct application of Newmark's sliding block method to the case of retaining walls are discussed with reference to a simple scheme of two interacting rigid blocks on an inclined plane. In particular, it is shown that both the internal force between the blocks and their absolute acceleration are not constant during sliding, and must be computed by direct consideration of the dynamic equilibrium and kinematic constraints for the whole system. The same concepts are extended to the analysis of the active soil wedge-wall system, leading to an extremely simple procedure to compute the relative displacements of the wall when subjected to base accelerations exceeding the critical value. A comparison with the results of numerical analyses demonstrates that the proposed method is capable of describing fully the kinematics of the soil wedge-wall system under dynamic loading. On the contrary, direct application of Newmark's method may lead to inaccurate predictions of the final displacements, in excess or in defect depending on a coefficient, which emerges from direct consideration of the dynamic equilibrium of the whole system. This coefficient can be viewed as a corrective factor for the horizontal relative acceleration of the wall, related to the mechanical and geometrical properties of the soil-wall system

The Halogen Bond in the Design of Functional Supramolecular Materials: Recent Advances

Halogen bonding is an emerging noncovalent interaction for constructing supramolecular assemblies. Though similar to the more familiar hydrogen bonding, four primary differences between these two interactions make halogen bonding a unique tool for molecular recognition and the design of functional materials. First, halogen bonds tend to be much more directional than (single) hydrogen bonds. Second, the interaction strength scales with the polarizability of the bond-donor atom, a feature that researchers can tune through single-atom mutation. In addition, halogen bonds are hydrophobic whereas hydrogen bonds are hydrophilic. Lastly, the size of the bond-donor atom (halogen) is significantly larger than hydrogen. As a result, halogen bonding provides supramolecular chemists with design tools that cannot be easily met with other types of noncovalent interactions and opens up unprecedented possibilities in the design of smart functional materials. This Account highlights the recent advances in the design of halogen-bond-based functional materials. Each of the unique features of halogen bonding, directionality, tunable interaction strength, hydrophobicity, and large donor atom size, makes a difference. Taking advantage of the hydrophobicity, researchers have designed small-size ion transporters. The large halogen atom size provided a platform for constructing all-organic light-emitting crystals that efficiently generate triplet electrons and have a high phosphorescence quantum yield. The tunable interaction strengths provide tools for understanding light-induced macroscopic motions in photoresponsive azobenzene-containing polymers, and the directionality renders halogen bonding useful in the design on functional supramolecular liquid crystals and gel-phase materials. Although halogen bond based functional materials design is still in its infancy, we foresee a bright future for this field. We expect that materials designed based on halogen bonding could lead to applications in biomimetics, optics/photonics, functional surfaces, and photoswitchable supramolecules

Supramolecular hierarchy among halogen and hydrogen bond donors in light-induced surface patterning

Halogen bonding, a noncovalent interaction possessing several unique features compared to the more familiar hydrogen bonding, is emerging as a powerful tool in functional materials design. Herein, we unambiguously show that one of these characteristic features, namely high directionality, renders halogen bonding the interaction of choice when developing azobenzene-containing supramolecular polymers for light-induced surface patterning. The study is conducted by using an extensive library of azobenzene molecules that differ only in terms of the bond-donor unit. We introduce a new tetrafluorophenol-containing azobenzene photoswitch capable of forming strong hydrogen bonds, and show that an iodoethynyl-containing azobenzene comes out on top of the supramolecular hierarchy to provide unprecedented photoinduced surface patterning efficiency. Specifically, the iodoethynyl motif seems highly promising in future development of polymeric optical and photoactive materials driven by halogen bonding

Surface segregation of conformationally asymmetric polymer blends

We have generalized the Edwards' method of collective description of dense polymer systems in terms of effective potentials to polymer blends in the presence of a surface. With this method we have studied conformationally asymmetric athermic polymer blends in the presence of a hard wall to the first order in effective potentials. For polymers with the same gyration radius $R_g$ but different statistical segment lengths $l_{A}$ and $l_{B}$ the excess concentration of stiffer polymers at the surface is derived as % \delta \rho _{A}(z=0)\sim (l_{B}^{-2}-l_{A}^{-2}){\ln (}R_{g}^{2}/l_{c}^{2}{)%}, where $l_{c}$ is a local length below of which the incompressibility of the polymer blend is violated. For polymer blends differing only in degrees of polymerization the shorter polymer enriches the wall.Comment: 11 pages, 7 figures, revtex