We analyze the nuclear magnetic relaxation rate (1/T1)orb due to the
coupling of nuclear spin to the orbital moment of itinerant electrons in
metals. In the clean non--interacting case, contributions from large--distance
current fluctuations add up to cause a divergence of (1/T1)orb. When
impurity scattering is present, the elastic mean free time τ cuts off the
divergence, and the magnitude of the effect at low temperatures is controlled
by the parameter ln(μτ), where μ is the chemical potential. The
spin--dipolar hyperfine coupling, while has the same spatial variation 1/r3
as the orbital hyperfine coupling, does not produce a divergence in the nuclear
magnetic relaxation rate.Comment: 11pages; v4: The analysis of the normal state is more compelete now,
including a comparison with other hyperfine interactions and a detailed
discussion of the effect in representative metals. The superconducting state
is excluded from consideration in this pape