Adam Valentine Sheridan Parry (16219013)

Colin Lambert (1316289)

Iain Mark Grace (16219016)

Mario Hoyos (1721380)

Marion Sofia Wrackmeyer (16219010)

Michael Lewis Turner (16219019)

Oscar Navarro (1589041)

Reiner Sebastian Sprick (2732641)

Polytriarylamines with extended fused backbones are accessible by the coupling of anilines with dibromoarenes based on substituted indenofluorenes, diindenofluorenes, carbazoles and indolocarbazoles. The optical and electrochemical properties of these polymers show an increase in the HOMO energy levels and the onset of absorption on extending the length of the fused ring segment. The polymer derived from the indenofluorene unit shows the highest reported performance for a polytriarylamine in an OFET and this observation can be rationalized by DFT calculations of model oligomers that show higher calculated reorganization energies for the more extended diindenofluorene units.Peer Reviewe

Sprick, R. S.

Hoyos, Mario

Wrackmeyer, M. S.

Sheridan Parry, A. V.

Grace, I. M.

Lambert, C.

Navarro, O.

Turner, M. L.

Digital.CSIC

Extended conjugation in poly(triarylamine)s: Synthesis, structure and impact on field-effect mobility

Reiner Sebastian Sprick

Mario Hoyos

Marion Sofia Wrackmeyer

Adam Valentine Sheridan Parry

Iain Mark Grace

Colin Lambert

Oscar Navarro

Michael Lewis Turner

Crossref

Journal of Materials Chemistry C

Extended conjugation in poly(triarylamine)s: synthesis, structure and impact on field-effect mobility

Polytriarylamines with extended fused backbones are accessible by the coupling of anilines with dibromoarenes based on substituted indenofluorenes, diindenofluorenes, carbazoles and indolocarbazoles. The optical and electrochemical properties of these polymers show an increase in the HOMO energy levels and the onset of absorption on extending the length of the fused ring segment. The polymer derived from the indenofluorene unit shows the highest reported performance for a polytriarylamine in an OFET and this observation can be rationalized by DFT calculations of model oligomers that show higher calculated reorganization energies for the more extended diindenofluorene units. This journal is © the Partner Organisations 2014

Sprick, Reiner Sebastian

Wrackmeyer, Marion Sofia

Parry, Adam Valentine Sheridan

Grace, Iain Mark

Lambert, Colin

Navarro, Oscar

Turner, Michael

The University of Manchester - Institutional Repository

Sussex Research Online

Polytriarylamines with extended fused backbones are accessible by the coupling of anilines with dibromoarenes based on substituted indenofluorenes, diindenofluorenes, carbazoles and indolocarbazoles. The optical and electrochemical properties of these polymers show an increase in the HOMO energy levels and the onset of absorption on extending the length of the fused ring segment. The polymer derived from the indenofluorene unit shows the highest reported performance for a polytriarylamine in an OFET and this observation can be rationalized by DFT calculations of model oligomers that show higher calculated reorganization energies for the more extended diindenofluorene units

Turner, Michael Lewis

Lancaster E-Prints

Extended conjugation in poly(triarylamine)s : synthesis, structure and impact on field-effect mobility

Energy Environ. Sci.,

Kline,performance of more extended diindenouorene polymers (3, PTAAs with extended fused backbones were synthesized by the (NHC)–Pd catalysed C–N coupling of anilines and dibromoarenes. The optical and electrochemical properties of these poly-J.

Synthesis,

https://hispana.mcu.es/es/registros/registro.do?tipoRegistro=MTD&idBib=17685794

Extended conjugation in poly(triarylamine)s: synthesis, structure and impact on field-effect mobility

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Digital.CSIC

Crossref

The University of Manchester - Institutional Repository

Sussex Research Online

Lancaster E-Prints

The University of Manchester - Institutional Repository