The Ultracold Neutron Asymmetry (UCNA) experiment was designed to measure the β-decay asymmetry parameter, A₀, for free neutron decay. In the experiment, polarized ultracold neutrons are transported into a decay trap, and their β-decay electrons are detected with ≈4π acceptance into two detector packages which provide position and energy reconstruction. The experiment also has sensitivity to b_n, the Fierz interference term in the neutron β-decay rate. In this work, we determine b_n from the energy dependence of A₀ using the data taken during the UCNA 2011-2013 run. In addition, we present the same type of analysis using the earlier 2010 A dataset. Motivated by improved statistics and comparable systematic errors compared to the 2010 data-taking run, we present a new b_n measurement using the weighted average of our asymmetry dataset fits, to obtain b_n = 0.066±0.041_(stat)±0.024_(syst) which corresponds to a limit of −0.012 < b_n < 0.144 at the 90% confidence level