Theory of electrostatically induced shape transitions in carbon nanotubes

Abstract

A mechanically bistable single-walled carbon nanotube can act as a variable-shaped capacitor with a voltage-controlled transition between collapsed and inflated states. This external control parameter provides a means to tune the system so that collapsed and inflated states are degenerate, at which point the tube's susceptibility to diverse external stimuli-- temperature, voltage, trapped atoms -- diverges following a universal curve, yielding an exceptionally sensitive sensor or actuator that is characterized by a vanishing energy scale. For example, the boundary between collapsed and inflated states can shift hundreds of Angstroms in response to the presence or absence of a single gas atom in the core of the tube. Several potential nano-electromechanical devices can be based on this electrically tuned crossover between near-degenerate collapsed and inflated configurations