Efficient heralded generation of entanglement together with its manipulation
is of great importance for quantum communications. In addition, states
generated with bandwidths naturally compatible with atomic transitions allow a
more efficient mapping of light into matter which is an essential requirement
for long distance quantum communications. Here we propose a scheme where the
indistinguishability between two spontaneous four-wave mixing processes is
engineered to herald generation of single-photon frequency-bin entangled
states, i.e., single-photons shared by two distinct frequency modes. We show
that entanglement can be optimised together with the generation probability,
while maintaining absorption negligible. Besides, the scheme illustrated for
cold rubidium atoms is versatile and can be implemented in several other
physical systems