Fabrication of Spherical Multi-Hollow TiO<sub>2</sub> Nanostructures for Photoanode Film with Enhanced Light-Scattering Performance

Abstract

Spherical multihollow (MH) TiO<sub>2</sub> nanostructures have been synthesized via a microemulsion-based approach with titanium glycerolate complexes formation at glycerol microemulsions interface. The self-aggregation of those microemulsions induces the formation of MH TiO<sub>2</sub> nanospheres. Owing to this hierarchical hollow structure, photoanode films derived from MH TiO<sub>2</sub> nanosphere as light scattering layer exhibits an enhanced light harvesting efficiency, thus leading to a 43% increment of photovoltaic performance compared to that from P25 nanoparticle film

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