In
this work, four 1-butyl-3-methylimidazolium carboxylate ionic
liquids (ILs) with different substituent groups in anions, including
1-butyl-3-methylimidazolium glycollate [C<sub>4</sub>mim][HOCH<sub>2</sub>COO], 1-butyl-3-methylimidazolium lactate [C<sub>4</sub>mim][CH<sub>3</sub>CHOHCOO], 1-butyl-3-methylimidazolium benzoate [C<sub>4</sub>mim][C<sub>6</sub>H<sub>5</sub>COO], and 1-butyl-3-methylimidazolium
glycinate [C<sub>4</sub>mim][H<sub>2</sub>NCH<sub>2</sub>COO], have
been synthesized and characterized. Their densities (ρ) and
surface tensions (γ) have been determined experimentally in
the temperature range of (298.15 to 343.15) K. By using thermodynamic
and empirical equations, molar volume (<i>V</i><sub>m</sub>), isobaric expansivity (α<sub><i>p</i></sub>), standard
entropy (<i>S</i>°), lattice energy (<i>U</i><sub>POT</sub>), surface excess entropy (<i>S</i><sub>s</sub>), vaporization enthalpy (Δ<sub>l</sub><sup>g</sup><i>H</i><sub>m</sub><sup>0</sup>) and Hildebrand solubility parameter
(δ<sub>H</sub>) of these ILs have been derived from density
and surface tension data. The effects of substituent groups in carboxylate
anions on densities and surface tensions of these ILs have been assessed
from the analysis of the structure–property relationship